UPDATED: 1 p.m.
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Deputy Fire Commissioner Craig Murphy said the fire is contained but it is not yet under control, and fire crews are making sure the fire does not spread.
He said a vat of butane caught fire. A series of smaller explosions happened as the fire worked its way through the tangle of pipes carrying fuel across the complex.
The Schuylkill eastbound ramp to 26th Street is closed.
Murphy said one PES employee was complaining of chest pains. Emergency personnel assessed him and determined that he did not need to be transported to the hospital, and they are treating him on site.
He says it's very fortunate nobody was hurt because there were people working nearby.
Thick, black smoke billowed across the city when the fire started.
To address air quality concerns, Murphy said that PES sent an industrial hygienist to monitor the air outside the area. Readings they received indicate the area is clear, and there is no danger to the public. PES will continue monitoring residential areas nearby.
A fireball in the sky
The initial explosion was both heard and felt by people all over the area. Some were a little too close to the action for comfort.
John Bonds was getting gas at a Wawa on Bartram Avenue just under five miles from the refinery when the sky lit up from the first explosion. After getting on the road, and being detoured through the city, Bonds says he stopped near a car dealership on Essington Avenue about two miles from the refinery to take a closer look.
"And I was about ready to pull out my phone and record the fire, and then a second explosion goes off, and I felt the heat coming off of that thing. And it was so ... so powerful," he said.
His reaction was one likely shared by many others.
But instead of taking off, Bob says that workers stayed put, at least for a little while.
"We were all standing there, and we said if we hear one more, we're leaving, you know? And as we we're standing there — boom!"
Bob and everyone else down in the area of the refinery were able to evacuate safely without any injuries.
Scarlett Rowe of Collingswood was driving his wife to the airport at around 4 a.m. with their 6-year-old daughter in the back seat. Shortly after crossing the Walt Whitman Bridge, he says they saw, heard and felt a massive explosion.
"Instantly the heat from the explosion just permeated the car," he said. "I mean, I had the AC on in the car, and the temperature in the car went from, like, 70 to 95 in a matter of, like, .5 seconds. It was crazy."
At the same time, Patrick Carmona was driving a tractor trailer northbound on the bridge when he saw the blast.
"That fire ball was huge. Just like a big movie explosion, where they want a lot of fire, not much smoke or anything, no clouds. It was a huge ball of fire," he said.
Kelly DeLeon said she looked up and saw fire in the sky as she drove across the Passyunk Avenue Bridge.
"When it exploded, it was shaking the bridge," she said. "So, I got off the bridge, because one thing's for sure: I didn't want to end up in the water in my car. Because that's what I thought would happen. It rattled so bad. And then I just got out of Dodge."
Philadelphia Energy Solutions says it is the largest oil-refining complex on the Eastern Seaboard.